Dexter-- A Theory of Sensitized Luminescence in Solids电子书...

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Citation: J. Chem. Phys. 21, 836 (1953); doi: 10.1063/1.1699044 View online: /10.1063/1.1699044 View Table of Contents: /resource/1/JCPSA6/v21/i5 Published by the American Institute of Physics. Additional information on J. Chem. Phys. Journal Homepage: / Journal Information: /about/about_the_journal Top downloads: /features/most_downloaded Information for Authors: /authors Downloaded 21 Aug 2012 to 42. Redistribution subject to AIP license or copyright; see /about/rights_and_permissions 836 L. F. H. BOVEY It is tempting to represent the data on CDaH and deviates widely from the observed value. Clearly the ef- CHaD by slightly different values of ro(C- H) and fect of zero-point vibration cannot be taken into account ro(C-D) (but neglecting the change in angle), as was in such a simple way. attempted in the case of the methyl halides by Miller The author wishes to thank Dr. A. E. Douglas for et alP However, here again a surprisingly large differ- suggesting the problem and for giving experimental and ence has to be assumed: one finds ro(C- H) = 1.0972 A, theoretical help. He is grateful to Dr. G. Herzberg for much helpful discussion. The cooperation of Dr. J. A. B. ro(C-D)=1.09021A. At the same time the moment of inertia of CH, would have to be 5.3719X 10-40, which Nolin and Dr. L. C. Leitch in supplying the deuterated methyl halides and of Dr. F. P. Lossing in analyzing 17 Mil
2018年11月14日Dexter-- A Theory of Sensitized Luminescence in Solids电子书.pdf,A Theory of Sensitized Luminescence in Solids D. L. Dexter Citation: J. Chem. Phys...Dexter-- A Theory of Sensitized Luminescence in Solids电子书.pdf,A Theory of Sensitized Luminescence in Solids D. L. Dexter Citation: J. Chem. Phys. 21, 836 (1953); doi: 10.1063/1.1699044 View online: /10.1063/1.1699044 View Table of Contents: /resource/1/JCPSA6/v21/i5 Published by the American Institute of PhysicDexter